Elsa Baquerizo/Amaranta Navarro, Spain (23) defeated Andrea Galindo/Claudia "Gorda" Galindo, Colombia (47) 2-0 (21-14, 21-17).
It was the first FIVB World Tour meeting between the two teams.
In Pool B, Spain is 2-0, advancing to the knockout phase, and Colombia is 0-2. Also in Pool B, Chantal Laboureur/Julia Sude of Germany is 2-0 and Cuba's Lidiannis Echeverria/Leila Martinez is 0-2.
Up next for Spain is Germany while Colombia plays Cuba. Both matches are Tuesday, 1 August.